On his way to becoming a Pokémon Master, Ash Ketchum and his companions continue on with their journey. But suddenly, a large mass enveloped in white smoke descends from the sky and lands in front of the group. Surrounding the area with white smoke, is a powerful Mythical Pokémon called Volcanion. Coming from the remote Nebel Plateau, Volcanion lives with Pokémon harmed by humans, and thus holds great distaste towards them. Ignoring the concerns of Ash and his friends, Volcanion immediately tries to leave, but a mysterious force binds Volcanion and Ash to each other. Finding themselves unable to separate, Ash is dragged along as Volcanion continues on its mission. In a city where large cogs and gears run continuously, a corrupt councillor of the Azoth Kingdom has obtained the ultimate invention: the Artificial Pokémon Magearna. Magearna was created 500 years ago and since lost, until the councillor found and kidnapped it from the Nebel Plateau. The councillor plans to use Magearna's mysterious power of its "Soul Heart" to take control of the mechanical kingdom. Now forced to work with each other, Ash and Volcanion must save Magearna from the corrupt councillor before he takes control of the Azoth Kingdom. A man and woman piloting an airship carrying a special container notice that their craft is being pursued by Volcanion. The woman, Cherie, tells her co-pilot Levi to go out and deal with Volcanion, who lands on the ship's deck. Levi sends out an Alakazam and Glalie, then uses a jeweled bracelet to activate a power he calls "Mega Wave", forcibly transforming his Pokémon into their Mega Evolved forms. Volcanion engages Mega Alakazam and Mega Glalie in battle, but Levi manages to fit an electronic band around one of its legs. Volcanion deflects a second band, but Levi has Mega Glalie freeze Volcanion in a block of ice before launching it off the ship. Ash and his friends continue their travels. Ash and Clemont have a battle to train, but shortly afterward, Volcanion crashes down onto the scene like an icy meteor. When the steam from Volcanion thawing clears, Ash discovers the band Volcanion deflected earlier now attached to himself. Volcanion tries to leave, only for Ash to be forcibly pulled to the band on its leg. Clemont discovers that the bands are forming a magnetic chain between Ash and Volcanion. Angered by the presence of humans near it, Volcanion flies off in pursuit of Levi and Cherie, taking Ash along unwillingly. En route, Volcanion briefly lands at a café, where Team Rocket notice Ash with it and decide to follow. At a castle, Levi and Cherie present the container to their boss, Cabinet Minister Alva, and a boy who is with him. It turns out to contain Magearna, a Pokémon. The boy introduces himself as Prince Raleigh of the Azoth Kingdom, the land where Magearna was originally born five hundred years prior. Volcanion suddenly appears with Ash, prompting Alva to activate Mega Wave on his Shiny Gengar along with Alakazam and Glalie using his staff. Volcanion is again frozen, and while Ash is stuck near it, Raleigh explains to him that Magearna is an artificial Pokémon created by the inventor Nikola, surprising him. Meanwhile, Raleigh's older sister Kimia launches her own flying device to observe Volcanion after being informed of its presence by her personal assistant, Flamel. As Volcanion thaws out, Ash's Pokémon arrive, and assist in overwhelming the three Mega Evolved Pokémon and creating enough confusion for Volcanion to escape with Magearna, angering Alva. Serena, Clemont and Bonnie arrive in the city looking for Ash with Dedenne using its electricity to find Pikachu,as Pikachu and the others flew ahead to go find Ash. Levi and Cherie soon find Team Rocket scaling the side of the castle and capture them. 
Under a bridge, Ash reunites with his Pokémon, along with Ash introducing himself and Pikachu to Magearna. Volcanion tries to keep humans away from Magearna, as it does not trust them, even when Ash offer to help them which Volcanion tells him it doesn't need help from humans prompting Pikachu to defend Ash. Pikachu then question as to why Volcanion doesn't want help from humans but Volcanion just tells Pikachu it will never trust them. Volcanion, who doesn't trust Pokémon that co-exist with humans either, offends Pikachu and Ash's other Pokémon for cozying up to humans getting them mad and ready to fight Volcanion but before anyone got a chance to attack Ash tries calming them down with Magearna's help to break up the fighting and scolded Volcanion. Pikachu feels something realizing it was Dedenne then Ash's friends arrive at the scene seeing Magearna they are a little astounded to see it. Meanwhile, Alva meets with Team Rocket in his office and realizes that they know Ash well. Seeing an opportunity, he recruits them to his cause. Clemont tries and fails to remove the bands bonding Ash and Volcanion together with Serena giving Ash new clothes to replace his water-damaged outfit. Ash and his friends are forced to accompany Volcanion and Magearna back to their home, the Nebel Plateau, under Magearna's suggestion and due to the bands still being stuck to Ash and Volcanion. That night, while en route to the Nebel Plateau, Ash's group are attacked by Team Rocket, who now possess Mega Wave bracelets supplied to them by Alva which they use to Mega Evolve the Heracross and Pinsir given to them. Ash and Volcanion try to fight them off while Serena, Clemont and Bonnie flee with Magearna, only for them to fall into a pit fall trap left by Team Rocket. To end the fight, Volcanion explodes using Steam Eruption; Kimia also appears with her own shiny Mega Gardevoir to defeat Team Rocket. Clemont gives Ash a protective suit he developed so that the next time Volcanion explodes, he will not be hurt. Kimia tells the group about Alva and her brother: Raleigh held a great interest in arcane science, the practices Nikola used, so Alva tutored him in both arcane science and the history of the Azoth Kingdom. Raleigh trusts Alva completely, but Kimia does not and suspects he holds an ulterior motive.
Under a bridge, Ash reunites with his Pokémon, along with Ash introducing himself and Pikachu to Magearna. Volcanion tries to keep humans away from Magearna, as it does not trust them, even when Ash offer to help them which Volcanion tells him it doesn't need help from humans prompting Pikachu to defend Ash. Pikachu then question as to why Volcanion doesn't want help from humans but Volcanion just tells Pikachu it will never trust them. Volcanion, who doesn't trust Pokémon that co-exist with humans either, offends Pikachu and Ash's other Pokémon for cozying up to humans getting them mad and ready to fight Volcanion but before anyone got a chance to attack Ash tries calming them down with Magearna's help to break up the fighting and scolded Volcanion. Pikachu feels something realizing it was Dedenne then Ash's friends arrive at the scene seeing Magearna they are a little astounded to see it. Meanwhile, Alva meets with Team Rocket in his office and realizes that they know Ash well. Seeing an opportunity, he recruits them to his cause. Clemont tries and fails to remove the bands bonding Ash and Volcanion together with Serena giving Ash new clothes to replace his water-damaged outfit. Ash and his friends are forced to accompany Volcanion and Magearna back to their home, the Nebel Plateau, under Magearna's suggestion and due to the bands still being stuck to Ash and Volcanion. That night, while en route to the Nebel Plateau, Ash's group are attacked by Team Rocket, who now possess Mega Wave bracelets supplied to them by Alva which they use to Mega Evolve the Heracross and Pinsir given to them. Ash and Volcanion try to fight them off while Serena, Clemont and Bonnie flee with Magearna, only for them to fall into a pit fall trap left by Team Rocket. To end the fight, Volcanion explodes using Steam Eruption; Kimia also appears with her own shiny Mega Gardevoir to defeat Team Rocket. Clemont gives Ash a protective suit he developed so that the next time Volcanion explodes, he will not be hurt. Kimia tells the group about Alva and her brother: Raleigh held a great interest in arcane science, the practices Nikola used, so Alva tutored him in both arcane science and the history of the Azoth Kingdom. Raleigh trusts Alva completely, but Kimia does not and suspects he holds an ulterior motive.
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